Composition for forming organic film, display device using the composition, and method of manufacturing the display device

ABSTRACT

A composition for forming organic film, a display device utilizing the composition, and a method of manufacturing the display device are provided. The composition for forming an organic film includes a solvent; and a compound of Formula 1:
 
Ar R) k .  Formula 1

CROSS-REFERENCE TO RELATED APPLICATION

This application claims priority to and the benefit of Korean Patent Application No. 10-2017-0088354, filed in the Korean Intellectual Property Office on Jul. 12, 2017, the disclosure of which is incorporated herein by reference in its entirety.

BACKGROUND 1. Field

The present disclosure relates to a composition for forming an organic film, a display device utilizing the composition, and a method of manufacturing the display device.

2. Description of the Related Art

Display devices have increasingly become more important in accordance with developments in multimedia technology. Accordingly, various kinds of display devices such as a liquid crystal display (LCD) device, an organic light-emitting display device, etc., have been utilized.

The organic light-emitting display device, which is a self-emissive display device, includes an organic light-emitting element. The organic light-emitting display device has many desired features such as wide viewing angles, excellent contrast, high response speed, superior luminance and driving voltage characteristics, and polychromaticity.

The organic light-emitting element has a structure in which organic films including a hole transfer layer and an emission layer are interposed between an anode electrode injecting holes and a cathode electrode injecting electrons. In response to a voltage applied between the anode electrode and the cathode electrode, holes and electrons recombine in the emission layer, thereby generating excitons. In response to the excitons relaxing from the excited state to the ground, state, light may be emitted.

SUMMARY

The organic films may be formed between the anode electrode and the cathode electrode by a fluid dispensing process such as inkjet printing. The fluid dispensing process can fabricate an organic film at only a particular location by discharging a composition for forming an organic film only to the particular location and drying and baking the composition.

However, the discharging of a composition for forming an organic film only to a desired location is not only very difficult, but may also cause an alignment defect due to a process error, which is a major cause of deterioration of the display quality of a display device. These problems may become more apparent as the resolution of the display device gradually increases. Accordingly, there is a limit in the resolution that can be achieved utilizing the fluid dispensing process.

An aspect according to exemplary embodiments of the present disclosure is directed toward a composition for forming an organic film utilizing a new method.

An aspect according to exemplary embodiments of the present disclosure is also directed toward a display device in which an organic film is formed utilizing a new method.

An aspect according to exemplary embodiments of the present disclosure is also directed toward a method of manufacturing a display device utilizing the composition for forming an organic film.

However, aspects of exemplary embodiments of the present disclosure are not restricted to those set forth herein. The above and other aspects of exemplary embodiments of the present disclosure will become more apparent to one of ordinary skill in the art to which the present disclosure pertains by referencing the detailed description of the present disclosure given below.

According to an exemplary embodiment of the present disclosure, a composition for forming an organic film includes: a solvent; and a compound of Formula 1: Ar

R)_(k)  Formula 1

In Formula 1, Ar is

Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group); Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₁₂ arylene group or a substituted or unsubstituted C₁₋₁₂ heteroarylene group); two or more of Ar₁₁, Ar₁₂, and Ar₁₅ may form a ring together, two or more of Ar₁₃, Ar₁₄, and Ar₁₆ may form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group); Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group); X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group); Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl or heteroaryl group (e.g., a substituted or unsubstituted C₈₋₁₀ aryl group or a substituted or unsubstituted C₁₋₁₀ heteroaryl group), Ar₃₅ and Ar₃₆ may form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl or heteroaryl group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group or a substituted or unsubstituted C₃₋₆₀ heteroaryl group); Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group), Ar₄₂ and Ar₄₃ may form a ring together; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, at least one of Ar₁₇, Ar₁₈, and Ar₁₉, at least one of Ar₂₁, and Ar₂₂, at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄, and at least one of Ar₄₂, and Ar₄₃ are divalent arylene or divalent heteroarylene groups, R is bonded thereto; R is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k is an integer between 2 and 4.

In an exemplary embodiment, the compound of Formula 1 may be a compound of Formula A-1, and the compound for forming the organic film may further include a compound of Formula E-1 or E-2:

In Formula A-1, Ar₁ is

Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ arylene, heteroaryl, or heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene or heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ may form a ring together, two or more of Ar₁₃, Ar₁₄, and Ar₁₆ may form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, and at least one of Ar₁₇, Ar₁₈, and Ar₁₉ are divalent arylene or divalent heteroarylene groups, R₁ is bonded thereto; R₁ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k1 is an integer between 2 and 4.

In an exemplary embodiment, the compound of Formula A-1 may be a compound of any one of Formulae A-2 through A-8:

In Formulae A-2 through Formula A-8, R₁₁, R₁₂, R₁₃, R₁₄, R₁₅, R₁₆, and R₁₇ are each independently a hydrogen atom,

two or more of R₁₁, R₁₂, R₁₃, and R₁₄ are each independently

two or more of R₁₅, R₁₆, and R₁₇ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9.

In an exemplary embodiment, the compound of Formula 1 may be a compound of Formula B-1, and the composition for forming the organic film may include the compound of Formula B-1: R₂—Ar₂—R₂′  Formula B-1

In Formula B-1, Ar₂ is

Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; R₂ and R₂′ are bonded to Ar₂₁ and Ar₂₂, respectively; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; R₂ and R₂′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9.

In an exemplary embodiment, the compound of Formula B-1 may be a compound of any one of Formulae B-2 through B-23:

In Formulae B-2 through B-23, R₂₁ and R₂₂ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group. In Formulae B-7 through B-9 and B-15 through B-20, X₁ is an oxygen atom or a sulfur atom, and in Formula B-14, X₂₁, X₂₂, X₂₃, X₂₄, X₂₅, X₂₆, X₂₇, and X₂₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group.

In an exemplary embodiment, the composition may further include: a compound of Formula C-1: Ar₃

R₃)_(k3)  Formula C-1

In Formula C-1, Ar₃ is

Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ is a divalent arylene or divalent heteroarylene group, R₃ is bonded thereto; Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl or heteroaryl group; Ar₃₅ and Ar₃₆ may form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; R₃ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k3 is an integer between 2 and 4.

In an exemplary embodiment, the compound of Formula C-1 may be a compound of any one of Formulae C-2 through C-16:

In Formulae C-2 through Formula C-16, R₃₁, R₃₂, R₃₃, and R₃₄ are each independently a hydrogen atom,

two or more of R₃₁, R₃₂, R₃₃, and R₃₄ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9; and in Formulae C-4 through C-9 and C-13 through C-16, X₁ and X₂ are each independently an oxygen atom or a sulfur atom.

In an exemplary embodiment, the compound of Formula 1 may be a compound of Formula D-1, and the composition for forming an organic film may further include a compound of Formula E-3 or E-4:

In Formula D-1, Ar₄

Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl or heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; Ar₄₂ and Ar₄₃ may form a ring together; R₄ and R₄′ are bonded to Ar₄₂ and Ar₄₃, respectively; R₄ and R₄′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9.

In an exemplary embodiment, the compound of Formula D-1 may be a compound of any one of Formulae D-2 through D-16:

In Formulae D-2 through D-16, R₄₁ and R₄₂ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9; and in Formulae D-10 through D-16, X₁ is an oxygen atom or a sulfur atom.

In an exemplary embodiment, the composition may further include: an initiator compound, wherein the solvent may be methyl benzoate, the compound of Formula 1 may be contained in an amount of about 1.0 weight percent (wt %) to 5.0 wt % with respect to the total weight of the composition for forming an organic film, the initiator compound may be contained in an amount of about 0.5 wt % to 4.0 wt % with respect to the total weight of the composition for forming an organic film, and the initiator compound may include a compound of any one of Formulae F-1, F-2, and F-3:

According to an exemplary embodiment of the present disclosure, a display device includes: a base; a plurality of anode electrodes on the base; a cathode electrode on the anode electrodes; and organic layers between the anode electrodes and the cathode electrode, wherein the organic layers include a polymer of a compound of Formula 1: Ar

R)_(k)  Formula 1

In Formula 1, Ar is

Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene or heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ may form a ring together, two or more of Ar₁₃, Ar₁₄, and Ar₁₆ may form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl or heteroaryl group; Ar₃₅ and Ar₃₆ may form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl or heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; Ar₄₂ and Ar₄₃ may form a ring together; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, at least one of Ar₁₇, Ar₁₈, and Ar₁₉, at least one of Ar₂₁, and Ar₂₂, at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄, and at least one of Ar₄₂, and Ar₄₃ are divalent arylene or divalent heteroarylene groups, R is bonded thereto; R is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k is an integer between 2 and 4.

In an exemplary embodiment, the organic layers may include a first organic layer between the anode electrodes and the cathode electrode, and the first organic layer may include a polymer of a compound of Formula A-1: Ar₁

R₁)_(k1)  Formula A-1

In Formula A-1, Ar₁ is

Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene or heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ may form a ring together; two or more of Ar₁₃, Ar₁₄, and Ar₁₆ may form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, and at least one of Ar₁₇, Ar₁₈, and Ar₁₉ are divalent arylene or divalent heteroarylene groups, R₁ is bonded thereto; R₁ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k1 is an integer between 2 and 4.

In an exemplary embodiment, the display device may include a first pixel configured to display a first color, a second pixel adjacent to the first pixel and configured to display a second color having a longer peak wavelength than the first color, and a third pixel adjacent to the first pixel and configured to display the first color, and the first organic layer in the first pixel may be physically spaced apart from the first organic layer in the third pixel.

In an exemplary embodiment, the organic layers may further include a second organic layer in the first pixel between the first organic layer and the cathode electrode, and the second organic layer may include a polymer of compounds of Formulae B-2 and C-1: R₂—Ar₂—R₂′  Formula B-1 Ar₃

R₃)_(k3)  Formula C-1

In Formula B-1, Ar₂ is

Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; R₂ and R₂′ are bonded to Ar₂₁ and Ar₂₂, respectively; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; R₂ and R₂′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9. In Formula C-1, Ar₃ is

Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; at one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ is a divalent arylene or divalent heteroarylene group, R₃ is bonded thereto; Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl or heteroaryl group; Ar₃₅ and Ar₃₆ may form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; R₃ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k3 is an integer between 2 and 4.

In an exemplary embodiment, the organic layers may further include a third organic layer in the second pixel between the first organic layer and the cathode electrode, and the third organic layer may include a polymer of a compound of Formula D-1: R₄—Ar₄—R₄′  Formula D-1

In Formula D-1, Ar₄ is

Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl or heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; Ar₄₂ and Ar₄₃ form a ring together; R₄ and R₄′ are bonded to Ar₄₂ and Ar₄₃, respectively; R₄ and R₄′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9.

In an exemplary embodiment, the organic layers may further include a fourth organic layer between the second organic layer and the cathode electrode and between the third organic layer and the cathode electrode, and the fourth organic layer in the first pixel may be physically formed in one integral body with the fourth organic layer in the third pixel.

According to an exemplary embodiment of the present disclosure, a method of manufacturing a display device includes: forming a coating layer by coating a base with a composition for forming an organic film; and forming organic layer patterns by patterning the coating layer, wherein the composition for forming an organic film includes a compound of Formula 1: Ar

R)_(k)  Formula 1

In Formula 1, Ar is

Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene or heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ may form a ring together; two or more of Ar₁₃, Ar₁₄, and Ar₁₆ may form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group; Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl or heteroaryl group; Ar₃₅ and Ar₃₆ may form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl or heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group, Ar₄₂ and Ar₄₃ form a ring together; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, at least one of Ar₁₇, Ar₁₈, and Ar₁₉, at least one of Ar₂₁, and Ar₂₂, at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄, and at least one of Ar₄₂, and Ar₄₃ are divalent arylene or divalent heteroarylene groups, R is bonded thereto; R is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9, and k is an integer between 2 and 4.

In an exemplary embodiment, the forming of the organic layer patterns may include placing a mask having openings over the coating layer, partially exposing and curing the coating layer by applying light, and developing the cured coating layer utilizing a developer.

In an exemplary embodiment, the method may further include, before the forming of the coating layer: forming an electrode layer on the base; and forming a bank having openings to expose the surface of the electrode layer.

In an exemplary embodiment, the method may further include, after the forming of the organic layer patterns: forming a bank having openings to expose the surfaces of the organic layer patterns.

The composition for forming an organic layer according to an exemplary embodiment of the present disclosure includes a photo-polymerizable reacting group and can thus form a patterned organic film through an exposure process. Accordingly, the fabrication of an organic light-emitting element can be relatively simplified, and an organic light-emitting element with high resolution can be realized.

The display device according to an exemplary embodiment of the present disclosure can improve display quality and reliability.

The method of manufacturing a display device according to an exemplary embodiment of the present disclosure can relatively simplify the fabrication of an organic light-emitting element and can realize an organic light-emitting element with high resolution.

Other features and exemplary embodiments may be apparent from the following detailed description, the drawings, and the claims.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are included to provide a further understanding of the inventive concepts, and are incorporated in and constitute a part of this specification, illustrate exemplary embodiments of the inventive concepts, and, together with the description, serve to explain principles of the inventive concepts.

FIG. 1 is a plan view of a display device according to an exemplary embodiment of the present disclosure;

FIG. 2 is a cross-sectional view taken along the line II-II′ of FIG. 1;

FIG. 3 is a cross-sectional view taken along the line of FIG. 1;

FIG. 4 is a cross-sectional view of a display device according to another exemplary embodiment of the present disclosure;

FIGS. 5 through 14 are cross-sectional views illustrating a method of manufacturing a display device according to an exemplary embodiment of the present disclosure; and

FIGS. 15 through 18 are cross-sectional views illustrating a method of manufacturing a display device according to another exemplary embodiment of the present disclosure.

DETAILED DESCRIPTION

Features of the invention and methods of accomplishing the same may be understood more readily by reference to the following detailed description of preferred embodiments and the accompanying drawings. The invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete and will fully convey the concept of the invention to those skilled in the art, and the invention will only be defined by the appended claims, and equivalents thereof.

It will be understood that when an element or layer is referred to as being “on,” “connected to” or “coupled to” another element or layer, the element or layer can be directly on, connected or coupled to another element or layer or intervening elements or layers. In contrast, when an element is referred to as being “directly on,” “directly connected to” or “directly coupled to” another element or layer, there are no intervening elements or layers present. As used herein, connected may refer to elements being physically, electrically and/or fluidly connected to each other.

Like numbers refer to like elements throughout. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.

It will be understood that, although the terms first, second, third, etc., may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the invention.

Spatially relative terms, such as “below,” “lower,” “under,” “above,” “upper” and the like, may be used herein for ease of description to describe the relationship of one element or feature to another element(s) or feature(s) as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation, in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” relative to other elements or features would then be oriented “above” relative to the other elements or features. Thus, the exemplary term “below” can encompass both an orientation of above and below. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein should be interpreted accordingly.

The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting. As used herein, the singular forms “a,” “an” and “the” are intended to include the plural forms as well, including “at least one,” unless the context clearly indicates otherwise. It will be further understood that the terms “comprises,” “comprising,” “includes” and/or “including,” when used in this specification, specify the presence of stated features, integers, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. “At least one” is not to be construed as limiting “a” or “an.” “Or” means “and/or.” As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.

In this disclosure, “*” denotes a binding site to which adjacent atoms are covalently bonded, and “C_(A-B)” denotes a carbon number of A to B. For example, a C₁₋₅ alkyl group refers to an alkyl group having 1 to 5 carbon atoms.

As used herein, the term “alkyl group” denotes a monovalent atomic group obtained by excluding one hydrogen atom from a linear or branched aliphatic saturated hydrocarbon and can be expressed as “*—C_(n)H_(2n+1) (where n is a natural number)”.

As used herein, the term “alkoxy group” denotes a monovalent atomic group having one alkyl group and one oxygen atom bonded thereto and can be expressed as “*—O—C_(n)H_(2n+1) (where n is a natural number)”.

As used herein, unless defined otherwise, the term “alkylene group” denotes a divalent atomic group obtained by excluding two hydrogen atoms from a straight or branched aliphatic saturated hydrocarbon and can be expressed as “*—C_(n)H_(2n)—* (where n is a natural number)”.

As used herein, the term “alkenyl group” denotes a monovalent atomic group obtained by excluding one hydrogen atom from an aliphatic unsaturated hydrocarbon having a double bond and can be expressed as “*—C_(n)H_(2n−1) (where n is a natural number)”.

As used herein, the term “alkynyl group” denotes a monovalent atomic group obtained by excluding one hydrogen atom from an aliphatic unsaturated hydrocarbon having a triple bond and can be expressed as “*—C_(n)H_(2n−3) (where n is a natural number)”.

As used herein, the term “alkylsilyl group” denotes a monovalent atomic group having an alkyl group and a silyl group bonded thereto.

As used herein, the term “aryl group” denotes a monovalent atomic group obtained by excluding one hydrogen atom from an aromatic hydrocarbon.

As used herein, the term “heteroaryl group” denotes an aryl group containing at least one atom other than carbon as an atom constituting a ring.

As used herein, the term “arylene group” denotes a divalent atomic group obtained by excluding two hydrogen atoms from an aromatic hydrocarbon.

As used herein, the term “heteroarylene group” denotes an arylene group containing at least one atom other than carbon as an atom constituting a ring.

As used herein, the term “arylsilyl group” denotes a monovalent atomic group having an aryl group and a silyl group bonded thereto.

As used herein, the term “aryloxy group” denotes a monovalent atomic group having an aryl group and an oxygen atom bonded thereto.

As used herein, the term “fused ring” denotes a ring formed by two or more ring groups bonded to share two or more atoms.

Compositions for forming an organic film according to exemplary embodiments of the present disclosure will hereinafter be described.

A composition for forming an organic film according to an exemplary embodiment of the present disclosure includes a compound of Formula 1 (i.e., a compound represented by Formula 1) below and a solvent. Ar

R)_(k)  Formula 1

In Formula 1, Ar, which forms the basic skeleton, is a divalent, trivalent or tetravalent aromatic group. Ar can impart a function to an organic film to be formed. For example, Ar may be expressed as

In

Ar₁₁, Ar₁₂, Ar₁₃, Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group), Ar₁₅ and Ar_(m) are each independently a substituted or unsubstituted C₆₋₁₂ arylene or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₁₂ arylene group or a substituted or unsubstituted C₁₋₁₂ heteroarylene group).

Two or more of Ar₁₁, Ar₁₂, and Ar₁₅ may form a ring together, and two or more of Ar₁₃, Ar₁₄, and Ar₁₆ may form a ring together.

In

Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group).

In

Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group), X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group.

In

Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl, arylene, heteroaryl, or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group), Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl or heteroaryl group (e.g., a substituted or unsubstituted C₆₋₁₀ aryl group or a substituted or unsubstituted C₁₋₁₀ heteroaryl group), Ar₃₅ and Ar₃₆ may form a ring together, and Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring.

In

Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl or heteroaryl group (e.g., a substituted or unsubstituted C₆₋₆₀ aryl group or a substituted or unsubstituted C₁₋₆₀ heteroaryl group), Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene or heteroarylene group (e.g., a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₃₋₆₀ heteroarylene group), and Ar₄₂ and Ar₄₃ may form a ring together.

If Ar₁₁, Ar₁₂, Ar₁₃, Ar₁₄, Ar₁₇, Ar₁₈, Ar₁₉, Ar₂₁, Ar₂₂, Ar₃₁, Ar₃₂, Ar₃₃, Ar₃₄, Ar₄₂, and Ar₄₃ are divalent arylene or heteroarylene groups, R may be bonded thereto. For example, at least one of Ar₁₁, Ar₁₂, Ar₁₃ and Ar₁₄, at least one of Ar₁₇, Ar₁₈ and Ar₁₉, at least one of Ar₂₁ and Ar₂₂, at least one of Ar₃₁, Ar₃₂, Ar₃₃ and Ar₃₄, and at least one of Ar₄₂ and Ar₄₃ are divalent arylene or divalent heteroarylene groups, and R may be bonded thereto.

R may be a photo-polymerizable reacting group. For example, the substituent R is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group, and j is an integer between 2 and 9.

k may define the number of substituents R bonded to Ar. For example, k is an integer between 2 and 4. If k=2, Ar is a divalent aromatic group. If k=3, Ar is a trivalent aromatic group. If k=4, Ar is a tetravalent aromatic group.

In one exemplary embodiment, the composition for forming an organic film may include the compound of Formula 1, and the compound of Formula 1 may be a compound of (i.e., a compound represented by) Formula A-1 below. Ar₁

R₁)_(k1)  Formula A-1

In Formula A-1, Ar₁, which forms the basic skeleton, is a divalent, trivalent or tetravalent aromatic group. For example, Ar₁ may be

Ar₁₁, Ar₁₂, Ar₁₃, Ar₁₄, Ar₁₅, Ar₁₆, Ar₁₇, Ar₁₈, and Ar₁₉ have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

If Ar₁₁, Ar₁₂, Ar₁₃, Ar₁₄, Ar₁₇, Ar₁₈, and Ar₁₉ are divalent arylene or heteroarylene groups, R₁ may be bonded thereto. For example, at least one of Ar₁₁, Ar₁₂, Ar₁₃ and Ar₁₄, and at least one of Ar₁₇, Ar₁₈ and Ar₁₉ are divalent arylene or divalent heteroarylene groups, and R may be bonded thereto.

The substituent R₁ may be a photo-polymerizable reacting group. For example, R₁ may be

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

k1 may define the number of substituents R₁ bonded to Ar₁. For example, k1 may be an integer between 2 and 4.

In a non-limiting example, the compound of Formula A-1 may be a compound of (i.e., a compound represented by) any one of Formulae A-2 through A-8 below.

In Formulae A-2 through A-8, R₁₁, R₁₂, R₁₃, R₁₄, R₁₅, R₁₆, and R₁₇ are each independently a hydrogen atom,

In a non-limiting example, two or more of R₁₁, R₁₂, R₁₃, and R₁₄ of Formulae A-2 through Formula A-7 may be each independently

in which case, the compounds of Formulae A-2 through A-7 may exhibit insolubility to a developer, which will be described in more detail later. In Formulae A-2 through A-7, R₁₁, R₁₂, R₁₃, and R₁₄ bonded to the benzene ring may be bonded to a carbon atom facing (i.e., in the para position to) the carbon atom bonded to the nitrogen atom. As a result, an anisotropic transition dipole can be allocated.

Two or more of R₁₅, R₁₆, and R₁₇ of Formula A-8 may be each independently

in which case, the compound of Formula A-8 may exhibit insolubility to the developer, which will be described in more later.

R₀ and j have already been described above with Formula 1, and detailed descriptions thereof will not be repeated.

The compounds of Formulae A-1 through A-8 may be, but are not limited to, compounds shown below.

The compounds of Formulae A-1 through A-8 and polymers thereof may have a hole injecting function and/or a hole transporting function. In an exemplary embodiment where the composition for forming an organic film includes the compounds of Formulae A-1 through A-8, the composition for forming the organic film may further include a compound of Formula E-1 or E-2 below.

In another exemplary embodiment, the composition for forming an organic film may include the compound of Formula 1, and the compound of Formula 1 may be a compound of (i.e., a compound represented by) Formula B-1. R₂—Ar₂—R₂′  Formula B-1

In Formula B-1, Ar₂, which forms the basic skeleton, is a divalent aromatic group. For example, Ar₂ may be

Ar₂₁, Ar₂₂, X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

Ar₂₁ and Ar₂₂ are each a divalent arylene or a divalent heteroarylene group, and R₂ and R₂′ may be bonded to Ar₂₁ and Ar₂₂, respectively. R₂ and R₂′ may each independently be a photo-polymerizable reacting group. For example, R₂ and R₂′ may be each independently

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

In a non-limiting example, the compound of Formula B-1 may be a compound of (i.e., a compound represented by) any one of Formulae B-2 through B-23.

In Formulae B-2 through B-23, R₂₁ and R₂₂ are each independently

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, X₁₈, X₂₁, X₂₂, X₂₃, X₂₄, X₂₅, X₂₆, X₂₇, and X₂₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group.

In Formulae B-7 through B-9 and B-15 through B-20, X₁ is an oxygen atom or a sulfur atom.

The compounds of Formulae B-1 through B-23 and polymers thereof may be utilized as a host material for a blue light-emitting material (e.g., a blue light-emitting layer).

The compounds of Formulae B-1 through B-23 may be, but are not limited to, compounds shown below.

In an exemplary embodiment where the composition for forming an organic film includes the compounds of Formulae B-1 through B-23, the composition for forming the organic film may further include a compound of Formula C-1 below. Ar₃

R₃)_(k3)  Formula C-1

In Formula C-1, Ar₃, which forms the basic skeleton, is a divalent, trivalent or tetravalent aromatic group. For example, Ar₃ may be

Ar₃₁, Ar₃₂, Ar₃₃, Ar₃₄, Ar₃₅, Ar₃₆, Ar₃₇, and Ar₃₈ have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

If Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are divalent arylene or heteroarylene groups, R₃ may be bonded thereto. The substituent R₃ may be a photo-polymerizable reacting group. For example, R₃ may be

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

k3 may define the number of substituents R₃ bonded to Ar₃. For example, k3 may be an integer between 2 and 4.

Ar₃₅ and Ar₃₆ may form a ring together. Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring which may be bonded to an adjacent benzene ring by sharing two or more carbon atoms.

In a non-limiting example, the compound of Formula C-1 may be a compound of any one of Formulae C-2 through C-16 below.

In Formulae C-2 through C-16, R₃₁, R₃₂, R₃₃, and R₃₄ may be each independently a hydrogen atom,

In a non-limiting example, two or more of R₃₁, R₃₂, R₃₃, and R₃₄ of Formulae C-2 through C-16 may be each independently

in which case, the compounds of Formulae C-2 through C-16 may exhibit insolubility to the developer, which will be described in more detail later. R₃₁, R₃₂, R₃₃, and R₃₄ bonded to the benzene ring may be bonded to a carbon atom facing (i.e., in the para position to) the carbon atom bonded to the nitrogen atom. As a result, an anisotropic transition dipole can be allocated.

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

In Formulae C-4 through C-9 and C-13 through C-16, X₁ and X₂ are each independently an oxygen atom or a sulfur atom.

The compounds of Formulae C-1 through C-16 and polymers thereof may be utilized as a dopant material for a blue light-emitting material (e.g., a blue light-emitting layer).

The compounds of Formulae C-1 through C-16 may be, but are not limited to, compounds shown below.

The compounds of Formulae B-1 through B-23 and C-1 through C-16 and polymers thereof may emit blue light.

In another exemplary embodiment, the composition for forming an organic film may include the compound of Formula 1, and the compound of Formula 1 may be a compound of Formula D-1 below. R₄—Ar₄—R₄′  Formula D-1

In Formula D-1, Ar₄, which forms the basic skeleton, is a divalent aromatic group. For example, Ar₄ may be

Ar₄₁, Ar₄₂, and A₄₃ have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

Ar₄₁ and Ar₄₂ are each a divalent arylene or heteroarylene group and form a ring together. R₄ and R₄′ may be bonded to Ar₂₁ and Ar₂₂, respectively. The substituents R₄ and R₄′ may be photo-polymerizable reacting group. For example, R₄ and R₄′ may be each independently

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

In a non-limiting example, the compound of Formula D-1 may be a compound of any one of Formulae D-2 through D-16.

In Formulae D-2 through D-16, R₄₁ and R₄₂ may be each independently

R₀ and j have already been described above in connection with Formula 1, and detailed descriptions thereof will not be repeated.

In Formulae D-10 through D-16, X₁ may be an oxygen atom or a sulfur atom.

The compounds of Formulae D-1 through D-16 may be, but are not limited to, compounds shown below.

The compounds of Formulae D-1 through D-16 and polymers thereof may be utilized as a host material for a red/green phosphorescent material (e.g., a red/green phosphorescent layer). In an exemplary embodiment where the composition for forming an organic film includes the compounds of Formulae D-1 through D-16, the composition for forming the organic film may further include a compound of Formula E-3 or E-4 below.

The composition for forming an organic film may include a solvent. The kind of the solvent is not particularly limited as long as it can properly disperse the compound of Formula 1. For example, the solvent may be methyl benzoate. In this example, the content of solids comprising the compound of Formula 1 may be about 1.0 weight percent (wt %) to 5.0 wt % with respect to the total weight of the composition for forming the organic film.

In some exemplary embodiments, the composition for forming an organic film includes the compound of Formula 1 and may further include an initiator compound. The content of the initiator compound may be about 0.5 wt % to 4.0 wt % with respect to the total weight of the composition for forming the organic film.

The initiator compound may be a cationic initiator compound. The cationic initiator compound may be a compound of any one of Formulae F-1 through F-3 below.

The preparation of the above-described compounds and composition will hereinafter be described in more detail.

Preparation Example 1: Synthesis of Compounds Preparation Example 1-1: Synthesis of Compound B119 Synthesis of Intermediate B119-3

3.60 g (10.46 mmol) of reactant B119-2 (4,4,5,5-tetramethyl-2-(4-(p-tolyl)naphthalen-1-yl)-1,3,2-dioxaborolane) and 0.216 g (0.188 mmol) of tetrakis(triphenylphosphine) palladium(0) were added to 3.63 g (10.46 mmol) of reactant B119-1 (9-bromo-10-(p-tolyl)anthracene) in a round flask, and the mixture was dissolved in 80 mL of tetrahydrofuran (THF). 40 mL of 2N aqueous sodium carbonate solution was added, and the mixture was refluxed for 24 hours. After cooled to room temperature, the mixture was poured into water, extracted with methylene chloride (MC), and dehydrated with MgSC₄, and the solvent was removed with a rotary evaporator. The resultant was purified utilizing column chromatography with CHCl₃ and was reprecipitated with methanol and THF to obtain 3.80 g of intermediate B119-3 (7.85 mmol, yield: 75%).

MS: m/z 484 [M]+

Synthesis of Intermediate B119-4

5.15 g (28.97 mmol) of N-bromosuccinimide (NBS) was slowly added to a solution a solution obtained by dissolving 6.84 g (14.13 mmol) of intermediate B119-3 (9-(p-tolyl)-10-(4-(p-tolyl)naphthalen-1-yl)anthracene) in 150 mL of dimethyl formamide (DMF). The mixture was reacted for 12 hours at room temperature. Then, the mixture was poured into brine and was extracted with MC. The extract was dehydrated with MgSC₄, and the solvent was removed with a rotary evaporator. The resultant was reprecipitated with methanol and THF to obtain 7.44 g of intermediate B119-4 (11.59 mmol, yield: 82%).

MS: m/z 642 [M]+

Synthesis of Compound B119

6.96 g (30.00 mmol) of reactant B110-5 (((5-((3-ethyloxetan-3-yl)methoxy)pentyl)oxy)methanol) was added to 9.63 g (15.00 mmol) of intermediate B119-4 (9-(4-(bromomethyl)phenyl)-10-(4-(4-(bromomethyl)phenyl)naphthalen-1-yl)anthracene), 20 g of 50% aqueous NaOH, and a 100 ml hexane solution. The mixture was refluxed for 2 hours. The mixture was cooled to room temperature, poured into water, extracted with diethyl ether, and dehydrated with MgSC₄. The solvent was removed with a rotary evaporator. The resultant was reprecipitated with methanol and THF to obtain 10.35 g of compound B119 (11.70 mmol, yield: 78%).

MS: m/z 884 [M]+

Preparation Example 1-2: Synthesis of Compound C102 Synthesis of Intermediate C102-3

5.4 g (15 mmol) of reactant C102-1 (1,6-dibromopyrene), 9.32 g (40 mmol) of reactant C102-2 (N-(p-tolyl)naphthalen-2-amine), 0.2 g (0.7 mmol) of palladium acetate (Pd(OAc)2), 6.7 g) of sodium tertiary butoxide, 6.7 g (69 mmol) of sodium tertiary butoxide, 0.14 g (0.7 mmol) of triturated butylphosphine, and 100 ml of toluene were added into a round flask and were reacted for 2 hours at 100° C. When the reaction was complete, the mixture was filtered, and the filtrate was concentrated and separated by column chromatography. The solid obtained by recrystallization utilizing toluene and methanol was filtered and dried to obtain 5.49 g of intermediate C102-3 (8.25 mmol, yield: 55%)

MS: m/z 664 [M]+

Synthesis of Intermediate C102-4

5.15 g (28.97 mmol) of NBS was slowly added to a solution obtained by dissolving 9.40 g (14.13 mmol) of intermediate C102-3 (N1,N6-di(naphthalen-2-yl)-N1,N6-di-p-tolylpyrene-1,6-diamine) in 150 ml of DMF. The mixture was reacted for 12 hours at room temperature, was poured into brine, and was extracted with MC. The extract was dehydrated with MgSC₄, and the solvent was removed with a rotary evaporator. The resultant was reprecipitated with methanol and THF to obtain 8.72 g of intermediate C102-4 (10.60 mmol, yield: 75%).

MS: m/z 822 [M]+

Synthesis of Compound C102

6.96 g (30.00 mmol) of reactant C102-5 (((5-((3-ethyloxetan-3-yl)methoxy)pentyl)oxy)methanol) was added to 12.35 g (15.00 mmol) of intermediate C102-4 (N1,N6-bis(4-(bromomethyl)phenyl)-N1,N6-di(naphthalen-2-yl)pyrene-1,6-diamine), 20 g of 50% aqueous NaOH, and a 100 ml hexane solution. The mixture was refluxed for 2 hours. The mixture was cooled to room temperature, poured into water, extracted with diethyl ether, and dehydrated with MgSO₄. The solvent was removed with a rotary evaporator. The resultant was reprecipitated with methanol and THF to obtain 11.97 g of compound C102 (11.25 mmol, yield: 75%).

MS: m/z 1064 [M]+

Preparation Example 2: Preparation of Composition for Forming Organic Film

Compositions for forming an organic film were prepared in accordance with the compositions shown in Tables 1 and 2 below.

The compound of Formula F-3 was utilized as an initiator compound, and methyl benzoate was utilized as a solvent.

The formulae of compounds B133 and B134 shown in Table 2 are as follows:

TABLE 1 Ingredients Preparation Examples Compound Initiator for Compositions for Contents Compound Forming Organic Film Compounds (wt %) Contents (wt %) HIL-1 A104 2.5 1.0 Formula E-1 HIL-2 A105 2.5 1.0 Formula E-1 HIL-3 A106 2.5 1.0 Formula E-1 HIL-4 A110 2.5 1.0 Formula E-1 HIL-5 A104 2.5 1.0 Formula E-2 HIL-6 A105 2.5 1.0 Formula E-2 HIL-7 A106 2.5 1.0 Formula E-2 HIL-8 A110 2.5 1.0 Formula E-2 HTL-1 A104 2.0 1.0 HTL-2 A105 2.0 1.0 HTL-3 A106 2.0 1.0 HTL-4 A110 2.0 1.0 B EML-1 B112 3.0 1.0 C102 B EML-2 B119 3.0 1.0 C102 B EML-3 B121 3.0 1.0 C102 B EML-4 B127 3.0 1.0 C102 B EML-5 B112 3.0 1.0 C104 B EML-6 B119 3.0 1.0 C104 B EML-7 B121 3.0 1.0 C104 B EML-8 B127 3.0 1.0 C104 B EML-9 B112 3.0 1.0 C116 B EML-10 B119 3.0 1.0 C116 B EML-11 B121 3.0 1.0 C116 B EML-12 B127 3.0 1.0 C116 B EML-13 B112 3.0 1.0 C123 B EML-14 B119 3.0 1.0 C123 B EML-15 B121 3.0 1.0 C123 B EML-16 B127 3.0 1.0 C123 G EML-1 D117 3.0 1.0 Formula E-3 G EML-2 D120 3.0 1.0 Formula E-3 G EML-3 D125 3.0 1.0 Formula E-3 G EML-4 D130 3.0 1.0 Formula E-3 G EML-5 D101 3.0 1.0 D117 Formula E-3 G EML-6 D101 3.0 1.0 D120 Formula E-3 G EML-7 D101 3.0 1.0 D125 Formula E-3 G EML-8 D101 3.0 1.0 D130 Formula E-3 R EML-1 D133 3.0 1.0 Formula E-4 R EML-2 D147 3.0 1.0 Formula E-4 R EML-3 D179 3.0 1.0 Formula E-4

TABLE 2 Ingredients Initiator Comparative Compound Compound Examples Compounds Contents (wt %) Contents (wt %) B EML-17 B133 3.0 1.0 C104 B EML-18 B133 3.0 5.0 C104 B EML-19 B134 3.0 1.0 C104

Preparation Example 3: Fabrication of Organic Light-Emitting Element Preparation Example 3-1

An ITO glass substrate (50 mm×50 mm, Samsung Corning's) was subjected to ultrasonic cleaning utilizing distilled water and isopropanol. Then, UV ozone cleaning was performed on the substrate for 30 minutes.

HIL-5 prepared in accordance with Preparation Example 2 was spin-coated on the cleaned substrate (i.e., the glass with the transparent electrode line adhered thereto) to form a film having a thickness of 60 nm, and was irradiated with ultraviolet light having a wavelength of 365 nm at a dose of 2 mJ/cm². Then, soft baking was performed at a temperature of 60° C. for 10 minutes, and the substrate was washed with methyl benzoate. Thereafter, hard baking was performed at a temperature of 150° C. for 30 minutes to form an organic film, i.e., a hole injection layer.

Thereafter, HTL-1 prepared in accordance with Preparation Example 2 was spin-coated on the hole injection layer to form a film having a thickness of 20 nm, and was irradiated with ultraviolet light having a wavelength of 365 nm at a dose of 2 mJ/cm². Then, soft baking was performed at 60° C. for 10 minutes, and the substrate was washed with methyl benzoate. Thereafter, hard baking was performed at a temperature of 150° C. for 30 minutes to form an organic film, i.e., a hole transport layer.

Thereafter, B EML-1 prepared in accordance with Preparation Example 2 was spin-coated on the hole transport layer to form a film having a thickness of 30 nm, and was irradiated with ultraviolet light having a wavelength of 365 nm at a dose of 2 mJ/cm². Then, soft baking was performed at 60° C. for 10 minutes, and the substrate was washed with methyl benzoate. Thereafter, hard baking was performed at a temperature of 140° C. for 30 minutes to form an organic film, i.e., a blue emission layer.

A compound of Formula G below was co-deposited with LiQ (8-Hydroxyquinolinolato-lithium) at a ratio of 5:5 on the blue emission layer to form an electron transport layer having a thickness of 20 nm.

LiQ was deposited on the electron transport layer to form an electron injection layer having a thickness of 1 nm, and then aluminum (Al) was deposited on the electron injection layer to form a cathode electrode having a thickness of 100 nm, thereby obtaining an organic light-emitting element. The deposition processes were performed utilizing Sunic System's Sunicel Plus 200.

Preparation Examples 3-2 Through 3-13

Organic light-emitting elements were fabricated utilizing compositions shown in Table 3 below and utilizing substantially the same method as the organic light-emitting element according to Preparation Example 3-1.

TABLE 3 Hole Injection Hole Transport Layer Layer Emission Layer Preparation HIL-7 HTL-3 B EML-5 Example 3-2 Preparation HIL-7 HTL-3 B EML-6 Example 3-3 Preparation HIL-7 HTL-3 B EML-7 Example 3-4 Preparation HIL-7 HTL-3 B EML-13 Example 3-5 Preparation HIL-7 HTL-3 B EML-14 Example 3-6 Preparation HIL-7 HTL-3 B EML-15 Example 3-7 Preparation HIL-5 HTL-1 G EML-5 Example 3-8 Preparation HIL-7 HTL-3 G EML-5 Example 3-9 Preparation HIL-7 HTL-3 G EML-6 Example 3-10 Preparation HIL-5 HTL-1 R EML-1 Example 3-11 Preparation HIL-7 HTL-3 R EML-1 Example 3-12 Preparation HIL-7 HTL-3 R EML-3 Example 3-13

Comparative Example 3-1

An organic light-emitting element was fabricated in substantially the same manner as the organic light-emitting element according to Preparation Example 3-7, except that a blue emission layer was formed utilizing B EML-17.

Comparative Example 3-2

An organic light-emitting element was fabricated in substantially the same manner as the organic light-emitting element according to Preparation Example 3-7, except that a blue emission layer was formed by forming a film utilizing B EML-17 and irradiating the film with UV light at a dose of 100 mJ/cm².

Comparative Example 3-3

An organic light-emitting element was fabricated in substantially the same manner as the organic light-emitting element according to Preparation Example 3-7, except that a blue emission layer was formed utilizing B EML-18.

Comparative Example 3-4

An organic light-emitting element was fabricated in substantially the same manner as the organic light-emitting element according to Preparation Example 3-7, except that a blue emission layer was formed utilizing B EML-19.

Experimental Example

The driving voltage, efficiency, color purity, and lifespan of each of the organic light-emitting elements according to Preparation Examples 3-1 through 3-13 and Comparative Examples 3-1 through 3-4 were measured, and the results of the measurement are as shown in Table 4 below.

Specifically, color coordinates, luminance, and efficiency were measured by supplying power from a current voltmeter (Keithley SMU 236) and utilizing a spectrophotometer (PR650).

T95 lifespan denotes the amount of time (hr) that it takes for luminance to decline to 95% from its initial level of 100% under a current condition of 10 mA/cm².

TABLE 4 Color Driving Efficiency Coordinates T95 Lifespan Voltage (V) (cd/A) CIEx CIEy (hr) Preparation 4.5 6.2 0.15 0.13 110 Example 3-1 Preparation 4.1 6.9 0.15 0.13 145 Example 3-2 Preparation 4.2 6.7 0.15 0.13 135 Example 3-3 Preparation 4.0 7.0 0.15 0.13 125 Example 3-4 Preparation 4.2 7.2 0.15 0.11 160 Example 3-5 Preparation 4.1 7.5 0.15 0.11 140 Example 3-6 Preparation 4.3 6.9 0.14 0.11 155 Example 3-7 Preparation 4.8 28.5 0.28 0.61 220 Example 3-8 Preparation 4.3 29.2 0.28 0.61 255 Example 3-9 Preparation 4.1 29.5 0.28 0.61 270 Example 3-10 Preparation 4.7 13.2 0.64 0.35 640 Example 3-11 Preparation 4.3 14.0 0.64 0.35 710 Example 3-12 Preparation 4.2 14.3 0.64 0.35 730 Example 3-13 Comparative 5.2 5.3 0.14 0.11 50 Example 3-1 Comparative 4.6 4.8 0.14 0.11 30 Example 3-2 Comparative 4.8 5.4 0.14 0.11 70 Example 3-3 Comparative 4.5 6.5 0.14 0.11 85 Example 3-4

Referring to Table 4, the organic light-emitting elements according to Preparation Examples 3-1 through 3-13 have a low driving voltage and at the same time, have a high efficiency and excellent color coordinates. Also, the organic light-emitting elements according to Preparation Examples 3-1 through 3-13 have a relatively long lifespan.

On the other hand, the organic light-emitting elements according to Comparative Examples 3-1 through 3-4 have a high driving voltage and a very short lifespan.

The results of the experiment conducted on the organic light-emitting elements according to Preparation Examples 3-1 through 3-13 and Comparative Examples 3-1 through 3-4 show that the compound of Formula 1 has excellent physical/chemical stability.

Display devices according to exemplary embodiments of the present disclosure and methods of manufacturing a display device according to exemplary embodiments of the present disclosure will hereinafter be described in more detail with reference to the accompanying drawings. Detailed descriptions of compounds and substituents that can be represented by the same formulae as those set forth hereinabove will not be repeated, which can be easily understood by a person skilled in the art.

FIG. 1 is a plan view of a display device according to an exemplary embodiment of the present disclosure. FIG. 2 is a cross-sectional view taken along the line II-II′ of FIG. 1. FIG. 3 is a cross-sectional view taken along the line of FIG. 1.

Referring to FIGS. 1 through 3, a plurality of pixels, which are arranged substantially in a matrix form on a plane, may be defined on a display device 1. In the description that follows, the term “pixel” refers to a single area defined, in a plan view, by dividing a display area for the display of a color, and a pixel can display a predetermined basic color. That is, a pixel may be a minimum (e.g., a smallest) unit of a display panel for displaying a color independently.

The plurality of pixels of the display device 1 include a first pixel PXa displaying a first color, a second pixel PXb displaying a second color having a longer peak wavelength than the first color, and a third pixel PXc displaying a third color having a longer peak wavelength than the second color. In one exemplary embodiment, the first pixel PXa, the second pixel PXb, and the third pixel PXc, which are illustrated as being sequentially arranged in a horizontal direction, may be repeatedly arranged one after another in the horizontal direction, forming a basic unit.

For example, the first pixel PXa may be a pixel displaying a blue color, the second pixel PXb may be a pixel displaying a green color, and the third pixel PXc may be a pixel displaying a red color. A fourth pixel PXd, which is adjacent to the first pixel PXa in a vertical direction, may be a pixel displaying the same color as the first pixel PXa.

The display device 1 includes a base 100, anode electrodes 200 and a cathode electrode 400, which are disposed on the base 100, and organic layers (500 a, 500 b, and 500 d), which are interposed between the anode electrodes 200 and the cathode electrode 400.

The base 100 may provide a space in which to dispose organic light-emitting elements. Although not specifically illustrated, the base 100 may include switching transistors and driving transistors for driving the organic light-emitting elements.

The anode electrodes 200 may be disposed on the base 100. The anode electrodes 200 may be electrically connected to the driving transistors of the base 100. The anode electrodes 200 may have a higher work function than the cathode electrode 400. The anode electrodes 200 may be transparent electrodes, opaque electrodes, or stacks of transparent electrodes and opaque electrodes. Examples of the material of the transparent electrodes include indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide, indium oxide, etc., and examples of the material of the opaque electrodes include lithium (Li), aluminum (Al), magnesium (Mg), silver (Ag), nickel (Ni), chromium (Cr), etc. The anode electrodes 200 may be disposed in the plurality of pixels, respectively, and may be supplied with driving signals independently of one another. That is, the anode electrode may include a plurality of anode electrodes patterned according to the plurality of pixels.

The cathode electrode 400 may have a relatively lower work function than the anode electrodes 200. The cathode electrode 400 and the anode electrodes 200 may be disposed on opposite sides of the organic layers (500 a, 500 b, and 500 d) and may drive the organic light-emitting elements together. The cathode electrode 400, like the anode electrodes 200, may be a transparent electrode, an opaque electrode, or a stack of the transparent electrodes and the opaque electrodes. The cathode electrode 400 may be disposed on substantially the entire surface of the base 100 without regard to the distinction between the plurality of pixels.

A bank 300 may be disposed on the base 100 and the anode electrodes 200. The bank 300 separates the plurality of pixels from one another. The bank 300 may at least partially overlap with the anode electrodes 200 and may have openings that at least partially expose the surfaces of the anode electrodes 200 therethrough. That is, the bank 300 may have openings that expose the anode electrodes 200 therethrough and may thus be substantially lattice-shaped in a plan view. The bank 300 may include an organic material such as a polyacrylic resin or a polyimide (PI) resin.

The organic layers (500 a, 500 b, and 500 d) may be interposed between the anode electrodes 200 and the cathode electrode 400. A first organic layer 500 a is disposed between the anode electrode 200 in the first pixel PXa and the cathode electrode 400, a second organic layer 500 b is disposed between the anode electrode 200 in the second pixel PXb and the cathode electrode 400, and a third organic layer 500 d may be disposed between the anode electrode 200 in the fourth pixel PXd and the cathode electrode 400. The first, second, and third organic layers 500 a, 500 b, and 500 d will hereinafter be described in more detail.

The first organic layer 500 a in the first pixel PXa may include a first hole injection layer 501 a, a first hole transport layer 502 a, a first emission layer 503 a, and a first electron injection layer 504 a. The second organic layer 500 b in the second pixel PXb may include a second hole injection layer 501 b, a second hole transport layer 502 b, a second emission layer 503 b, and a second electron injection layer 504 b. The third organic layer 500 d in the fourth pixel PXd may include a third hole injection layer 501 d, a third hole transport layer 502 d, a third emission layer 503 d, and a third electron injection layer 504 d.

The first, second, and third hole injection layers 501 a, 501 b, and 501 d may facilitate the injection of holes from the anode electrodes 200. The first, second, and third hole injection layers 501 a, 501 b, and 501 d may be disposed on the base 100 and the bank 300.

The first, second, and third hole injection layers 501 a, 501 b, and 501 d may include the same material.

In one exemplary embodiment, the first, second, and third hole injection layers 501 a, 501 b, and 501 d may include a polymer of a compound of Formula 1. For example, the first, second, and third hole injection layers 501 a, 501 b, and 501 d may include a polymer of a compound of Formula A-1. In some exemplary embodiments, the first, second, and third hole injection layers 501 a, 501 b, and 501 d may further include a compound of Formula E-1 or E-2.

The polymerization of compounds of Formula A-1 may occur at the terminal photo-polymerizable groups. Compounds of Formulae A-2 through A-8, which are specific examples of a compound of Formula A-1, and their respective substituents have already been described above, and detailed descriptions thereof will not be repeated.

In a non-limiting example, the first, second, and third hole injection layers 501 a, 501 b, and 501 d may include a polymer main chain of (i.e., represented by) any one of Formulae 2A through 2C below.

In Formulae 2A, 2B, and 2C, R₀ may be a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j1 and j2 may be each independently an integer of 2 to 9; and n, which defines the repeating unit of the polymer main chain, may be an integer of 1 to 100.

In Formulae 2A, 2B, and 2C, L₁ and L₂ may be parts originating from (e.g., branched from) the basic skeletons of the compounds of Formulae A-1 through A-8.

The first hole injection layer 501 a in the first pixel PXa and the second hole injection layer 501 b in the second pixel PXb may be physically spaced apart from each other. The first hole injection layer 501 a in the first pixel PXa and the third hole injection layer 501 d in the fourth pixel PXd may be physically spaced apart from each other. By physically separating the first, second, and third hole injection layers 501 a, 501 b, and 501 d, which have conductivity, from one another, a lateral leakage current that may be formed between the plurality of pixels may be prevented.

The first, second, and third hole transport layers 502 a, 502 b, and 502 d may facilitate the transfer of holes provided from the anode electrodes 200. The first, second, and third hole transport layers 502 a, 502 b, and 502 d may be disposed on the hole injection layers 501 a, 501 b, and 501 d and the bank 300.

The first, second, and third hole transport layers 502 a, 502 b, and 502 d may include the same material.

In one exemplary embodiment, the first, second, and third hole transport layers 502 a, 502 b, and 502 d may include a polymer of a compound of Formula 1. The polymerization of compounds of Formula A-1 may occur at the terminal photo-polymerizable groups. Compounds of Formulae A-2 through A-8, which are specific examples of a compound of Formula A-1, and their respective substituents have already been described above, and detailed descriptions thereof will not be repeated.

In a non-limiting example, the first, second, and third hole transport layers 502 a, 502 b, and 502 d may include the polymer main chain of any one of Formulae 2A through 2C.

The first hole transport layer 502 a in the first pixel PXa and the second hole transport layer 502 b in the second pixel PXb may be physically spaced apart from each other. The first hole transport layer 502 a in the first pixel PXa and the third hole transport layer 502 d in the fourth pixel PXd may be physically spaced apart from each other.

The first, second, and third emission layers 503 a, 503 b, and 503 d may generate light by recombining holes provided from the anode electrodes 200 and electrons provided from the cathode electrode 400. Specifically, as a result of the recombination of the holes and the electrons, excitons may be generated, and as the excitons relax from the excited state to the ground state, light may be emitted from the excitons. The first and third emission layers 503 a and 503 d may be, but are not limited to, blue emission layers, and the second emission layer 503 b may be, but is not limited to, a green emission layer. The first, second, and third emission layers 503 a, 503 b, and 503 d may be disposed on the first, second, and third hole transport layers 502 a, 502 b, and 502 d and the bank 300.

In one exemplary embodiment, the first and third emission layers 503 a and 503 d may include a polymer of the compound of Formula 1. For example, the first and third emission layers 503 a and 503 d may include a polymer of compounds of Formula B-1, a polymer of compounds of Formula C-1, and/or a polymer (e.g., a copolymer) of a compound of Formula B-1 and a compound of Formula C-1. The polymerization of compounds of Formula B-1, the polymerization of compounds of Formula C-1, and/or the polymerization of a compound of Formula B-1 and a compound of Formula C-1 may occur at the terminal photo-polymerization groups. Compounds of Formulae B-1 through B-23 and C-1 through C-16, which are specific examples of a compound of Formula B-1 or C-1, and their respective substituents have already been described above, and detailed descriptions thereof will not be repeated.

The second emission layer 503 b may include a polymer of the compound of Formula 1. For example, the second emission layer 503 b may include a polymer of a compound of Formula D-1. The polymerization of compounds of Formula D-1 may occur at the terminal photo-polymerization groups. Compounds of Formulae D-1 through D-16, which are specific examples of a compound of Formula D-1, and their respective substituents have already been described above, and detailed descriptions thereof will not be provided.

In a non-limiting example, the first, second, and third emission layers 503 a, 503 b, and 503 d may include a polymer main chain of any one of Formulae 2A through 2C.

In Formulae 2A, 2B, and 2C, L₁ and L₂ may be parts originating (e.g., branching) from the basic skeletons of the compounds of Formulae B-1 through B-23, C-1 through C-16, or D-1 through D-16.

The first emission layer 503 a in the first pixel PXa and the second emission layer 503 b in the second pixel PXb may be physically spaced apart from each other. The first emission layer 503 a in the first pixel PXa and the third emission layer 503 d in the fourth pixel PXd may be physically spaced apart from each other.

The first, second, and third electron injection layers 504 a, 504 b, and 504 d may facilitate the injection of electrons from the cathode electrode 400. The first, second, and third electron injection layers 504 a, 504 b, and 504 d may be disposed on the first, second, and third emission layers 503 a, 503 b, and 503 d and the bank 300.

The first, second, and third electron injection layers 504 a, 504 b, and 504 d may include the same material.

The first electron injection layer 504 a in the first pixel PXa and the second electron injection layer 504 b in the second pixel PXb may be physically spaced apart from each other. The first electron injection layer 504 a in the first pixel PXa and the third electron injection layer 504 d in the fourth pixel PXd may be physically connected to each other and may be formed in one integral body with each other.

Although not specifically illustrated, a functional layer such as an electron transfer layer may be further interposed between the first emission layer 503 a and the first electron injection layer 504 a, between the second emission layer 503 b and the second electron injection layer 504 b, or between the third emission layer 503 d and the third electron injection layer 504 d.

A display device according to another exemplary embodiment of the present disclosure will hereinafter be described in more detail.

FIG. 4 is a cross-sectional view of a display device according to another exemplary embodiment of the present disclosure.

Referring to FIG. 4, a display device 2 differs from the display device 1 according to the exemplary embodiment of FIG. 1 in that a bank 300 is disposed on the first and second emission layers 513 a and 513 b.

In one exemplary embodiment, the first and second organic layers 510 a and 510 b may be disposed between anode electrodes 200 and a cathode electrode 400. The first organic layer 510 a may be disposed in a first pixel displaying a blue color, and the second organic layer 510 b may be disposed in a second pixel displaying a green color.

The first organic layer 510 a may include a first hole injection layer 511 a, a first hole transport layer 512 a, the first emission layer 513 a, and a first electron injection layer 514 a. The first emission layer 513 a may be, but is not limited to, a blue emission layer. The second organic layer 510 b may include a second hole injection layer 511 b, a second hole transport layer 512 b, the second emission layer 513 b, and a second electron injection layer 514 b. The second emission layer 513 b may be, but is not limited to, a green emission layer. The first and second organic layers 510 a and 510 b have been already described above with reference to FIGS. 1 through 3, and thus, detailed descriptions thereof will be omitted.

The bank 300 may be disposed on the first and second emission layers 513 a and 513 b. The bank 300 may at least partially overlap with the anode electrodes 200, the first hole injection layer 511 a, the first hole transport layer 512 a, the first emission layer 513 a, the second hole injection layer 511 b, the second hole transport layer 512 b, and the second emission layer 513 b and may have openings that at least partially expose the surfaces of the first and second emission layers 513 a and 513 b therethrough.

Methods of manufacturing a display device according to exemplary embodiments of the present disclosure will hereinafter be described in more detail.

FIGS. 5 through 14 are cross-sectional views illustrating a method of manufacturing a display device according to an exemplary embodiment of the present disclosure.

Referring to FIG. 5, anode electrodes 200 and a bank 300 are formed on a base 100.

The anode electrodes 200 may be disposed on the base 100. The anode electrodes 200 may be electrically connected to driving transistors of the base 100. The anode electrodes 200 may be disposed in pixels, respectively, by forming an electrode layer and then patterning the electrode layer.

The bank 300 may be disposed on the anode electrodes 200. The bank 300 may have openings that at least partially expose the surfaces of the anode electrodes 200 therethrough. The bank 300 may be substantially lattice-shaped in a plan view.

The anode electrodes 200 and the bank 300 have already been described above with reference to FIG. 3, and detailed descriptions thereof will not be repeated.

Thereafter, referring to FIG. 6, a first coating layer 551 is formed by coating the anode electrodes 200 and the bank 300 with a composition for forming an organic film. A coating method utilized to form the first coating layer 551 is not particularly limited, but for example, spin coating or slit coating may be utilized.

In one exemplary embodiment, the composition utilized to form the first coating layer 551 and the first coating layer 551 may include a compound of Formula 1. For example, the first coating layer 551 may include a compound of Formula A-1 and may further include a compound of Formula E-1 or E-2. Compounds of Formulae A-2 through A-8, which are specific examples of the compound of Formula A-1, and substituents thereof have been already described above, and detailed descriptions thereof will not be repeated.

Thereafter, referring to FIG. 7, organic layer patterns are formed by patterning the first coating layer 551 of FIG. 6. An act of forming the organic layer patterns of FIG. 7 may be an act of forming the first and second hole injection layer patterns 501 a and 501 b in the first and second pixels, respectively, by patterning the first coating layer 551.

In one exemplary embodiment, the act of forming the organic layer patterns of FIG. 7 may include: placing a mask M1; partially exposing and curing the first coating layer 551 of FIG. 6 by applying light; and forming the first and second hole injection layer patterns 501 a and 501 b, which are exposed and cured, utilizing a developer.

The composition utilized to form the first coating layer 551 and the first coating layer 551 may include the compound of Formula A-1, which has a photo-polymerizable reacting group, and may thus have negative photosensitivity so that part thereof that is exposed to light may be photo-cured. Accordingly, the organic layer patterns of FIG. 7 can be precisely formed at any desired locations without the need of a complex process.

Thereafter, referring to FIG. 8, a second coating layer 552 is formed by coating the first and second hole injection layer patterns 501 a and 501 b with a composition for forming an organic layer.

In one exemplary embodiment, the composition utilized to form the second coating layer 552 and the second coating layer 552 may include the compound of Formula 1. For example, the second coating layer 552 may include the compound of Formula A-1. Compounds of Formulae A-2 through A-8, which are specific examples of the compound of Formula A-1, and their respective substituents have been already described above, and detailed descriptions thereof will not be repeated.

Thereafter, referring to FIG. 9, organic layer patterns are formed by patterning the second coating layer 552 of FIG. 8. An act of forming the organic layer patterns of FIG. 9 may be an act of forming the first and second hole transfer layer patterns 502 a and 502 b in the first and second pixels, respectively, by patterning the second coating layer 552.

In one exemplary embodiment, the act of forming the organic layer patterns of FIG. 9 may include: placing a mask M2; partially exposing and curing the second coating layer 552 of FIG. 8 by applying light; and forming the first and second hole transfer layer patterns 502 a and 502 b, which are exposed and cured, utilizing a developer.

The composition utilized to form the second coating layer 552 and the second coating layer 552 may include the compound of Formula A-1, which has a photo-polymerizable reacting group, and may thus have negative photosensitivity so that part thereof that is exposed to light may be photo-cured. Accordingly, the organic layer patterns of FIG. 9 can be precisely formed at any desired locations without the need of a complex process.

Thereafter, referring to FIG. 10, a third coating layer 553 a is formed by coating the first and second hole transport layer patterns 502 a and 502 b with a composition for forming an organic film.

In one exemplary embodiment, the composition utilized to form the third coating layer 553 a and the third coating layer 553 a may include the compound of Formula 1. For example, the third coating layer 553 a may include a compound of Formula B-1 and/or a compound of Formula C-1. Compounds of Formulae B-2 through B-23 and C-2 through C-16, which are specific examples of the compound of Formula B-1 or C-1, and their respective substituents have been already described above, and detailed descriptions thereof will not be repeated.

Thereafter, referring to FIG. 11, an organic layer pattern is formed by patterning the third coating layer 553 a of FIG. 10. An act of forming the organic layer pattern of FIG. 11 may be an act of forming a first emission layer pattern 503 a in the first pixel by patterning the third coating layer 553 a.

In one exemplary embodiment, the act of forming the organic layer pattern of FIG. 11 may include: placing a mask M3; partially exposing and curing the third coating layer 553 a of FIG. 10 by applying light; and forming the first emission layer pattern 503 a, which is exposed and cured, utilizing a developer.

The composition utilized to form the third coating layer 553 a and the third coating layer 553 a may include the compound of Formula B-1, which has a photo-polymerizable reacting group, and/or the compound of Formula C-1, which also has a photo-polymerizable reacting group, and may thus have negative photosensitivity so that part thereof that is exposed to light may be photo-cured. Accordingly, the organic layer pattern of FIG. 11 can be precisely formed at any desired location without the need of a complex process.

Thereafter, referring to FIG. 12, a fourth coating layer 553 b is formed by coating the first emission layer pattern 503 a and the second hole transport layer pattern 502 b with a composition for forming an organic film.

In one exemplary embodiment, the composition utilized to form the fourth coating layer 553 b and the fourth coating layer 553 b may include the compound of Formula 1. For example, the fourth coating layer 553 b may include a compound of Formula D-1 and may further include a compound of Formula E-3 or E-4. Compounds of Formulae D-2 through D-16, which are specific examples of the compound of Formula D-1, and their respective substituents have already been described above, and detailed descriptions thereof will not be repeated.

Thereafter, referring to FIG. 13, an organic layer pattern is formed by patterning the fourth coating layer 553 b of FIG. 12. An act of forming the organic layer pattern of FIG. 13 may be an act of forming a second emission layer pattern 503 b in the second pixel by patterning the fourth coating layer 553 b.

In one exemplary embodiment, the act of forming the organic layer pattern of FIG. 13 may include placing a mask M4; partially exposing and curing the fourth coating layer 553 b of FIG. 12 by applying light; and forming the second emission layer pattern 553 b, which is exposed and cured, utilizing a developer.

The composition utilized to form the fourth coating layer 553 b and the fourth coating layer 553 b may include the compound of Formula D-1, which has a photo-polymerizable reacting group, and may thus have negative photosensitivity so that part thereof that is exposed may be photo-cured. Accordingly, the organic layer pattern of FIG. 13 can be precisely formed at any desired location without the need of a complex process.

Thereafter, referring to FIG. 14, first and second electron injection layer patterns 504 a and 504 b are formed on the first and second emission layer patterns 503 a and 503 b, respectively, and a cathode electrode 400 is formed.

A method of manufacturing a display device according to another exemplary embodiment of the present disclosure will hereinafter be described in more detail.

FIGS. 15 through 18 are cross-sectional views illustrating a method of manufacturing a display device according to another exemplary embodiment of the present disclosure.

Referring to FIG. 15, anode electrodes 200 and the first and second hole injection layer patterns 511 a and 511 b are formed on a base 100. The formation of the first and second hole injection layer patterns 511 a and 511 b has been already described above with reference to FIGS. 6 and 7, and a detailed description thereof will not be repeated.

Thereafter, referring to FIG. 16, the first and second hole transport layer patterns 512 a and 512 b are formed on the first and second hole injection layer patterns 511 a and 511 b, respectively. The formation of the first and second hole transport layer patterns 512 a and 512 b has been already described above with reference to FIGS. 8 and 9, and a detailed description thereof will not be repeated.

Thereafter, referring to FIG. 17, the first and second emission layer patterns 513 a and 513 b are formed on the first and second hole transport layer patterns 512 a and 512 b, respectively. The formation of the first and second emission layer patterns 513 a and 513 b has been already described above with reference to FIGS. 10 through 13, and a detailed description thereof will not be repeated.

Thereafter, a bank 300 is formed on the first and second emission layer patterns 513 a and 513 b, and the first and second electron injection layer patterns 514 a and 514 b are formed.

In one exemplary embodiment, the bank 300 may be formed to have openings that at least partially expose the surfaces of the first and second emission layer patterns 513 a and 513 b therethrough. The bank 300 may be substantially lattice-shaped in a plan view. The first and second electron injection layer patterns 514 a and 514 b may be disposed on the bank 300.

In another exemplary embodiment, the first hole injection layer pattern 511 a, the first hole transport layer pattern 512 a, and the first emission layer pattern 513 a may be formed at the same time by patterning. That is, the first hole injection layer pattern 511 a, the first hole transport layer pattern 512 a, and the first emission layer pattern 513 a may be formed at the same time by performing exposure and curing utilizing a single mask. In this case, the sides of the first hole injection layer pattern 511 a, the sides of the first hole transport layer pattern 512 a, and the sides of the first emission layer pattern 513 a may all be aligned.

Similarly, the second hole injection layer pattern 511 b, the second hole transport layer pattern 512 b, and the second emission layer pattern 513 b may be formed at the same time by patterning. That is, the second hole injection layer pattern 511 b, the second hole transport layer pattern 512 b, and the second emission layer pattern 513 b may be formed at the same time by performing exposure and curing utilizing a single mask. In this case, the sides of the second hole injection layer pattern 511 b, the sides of the second hole transport layer pattern 512 b, and the sides of the second emission layer pattern 513 b may all be aligned.

While the present invention has been particularly illustrated and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and detail may be made therein without departing from the spirit and scope of the present invention as defined by the following claims, and equivalents thereof. The exemplary embodiments should be considered in a descriptive sense only and not for purposes of limitation. 

What is claimed is:
 1. A composition for forming an organic film, comprising: a solvent; and a compound of Formula 1: Ar

R)_(k)  Formula 1 wherein in Formula 1, Ar is

Ar₁₁, Ar₁₂, Ar₁₃ and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene group or a substituted or unsubstituted C₁₋₁₂ heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ optionally form a ring together; two or more of Ar₁₃, Ar₁₄, and Ar₁₆ optionally form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl group or a substituted or unsubstituted C₁₋₁₀ heteroaryl group; Ar₃₅ and Ar₃₆ optionally form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl group or a substituted or unsubstituted C₃₋₆₀ heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₃₋₆₀ heteroarylene group; Ar₄₂ and Ar₄₃ form a ring together; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, at least one of Ar₁₇, Ar₁₈, and Ar₁₉, at least one of Ar₂₁, and Ar₂₂, at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄, and at least one of Ar₄₂, and Ar₄₃ are divalent arylene or divalent heteroarylene groups, R is bonded thereto; R is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and k is an integer between 2 and 4, wherein when the compound of Formula 1 is a compound represented by Formula A-2: R₁₁ to R₁₄ are each independently a hydrogen atom or

two or more of R₁₁, R₁₂, R₁₃, and R₁₄ are each independently

and j is an integer between 2-9; and wherein when two selected from R₁₁ to R₁₄ of Formula A-2 are each a hydrogen atom, and another two of R₁₁ to R₁₄ are each represented by

j is an integer between 2-5 or 7-9: Formula A-2

and wherein the compound of Formula 1 is contained in an amount of 1.0 weight percent (wt %) to 5.0 wt % with respect to a total weight of the composition for forming the organic film.
 2. The composition of claim 1, wherein the compound of Formula 1 is a compound of Formula A-1, and the composition for forming the organic film further comprises a compound of Formula E-1 or E-2:

wherein in Formula A-1, Ar₁ is

Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene group or a substituted or unsubstituted C₁₋₁₂ heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ optionally form a ring together, two or more of Ar₁₃, Ar₁₄, and Ar₁₆ optionally form a ring together, Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, and at least one of Ar₁₇, Ar₁₈, and Ar₁₉ are divalent arylene or divalent heteroarylene groups, R₁ is bonded thereto; R₁ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and k1 is an integer between 2 and
 4. 3. The composition of claim 2, wherein the compound of Formula A-1 is a compound of any one of Formulae A-2 through A-8:

wherein in Formula A-2, R₁₁, R₁₂, R₁₃, R₁₄ and j are the same as defined in claim 1, and wherein in Formulae A-3 through Formula A-8, R₁₁, R₁₂, R₁₃, R₁₄, R₁₅, R₁₆, and R₁₇ are each independently a hydrogen atom,

two or more of R₁₁, R₁₂, R₁₃, and R₁₄ are each independently

two or more of R₁₅, R₁₆, and R₁₇ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and
 9. 4. The composition of claim 1, wherein the compound of Formula 1 is a compound of Formula B-1, and the composition for forming the organic film comprises the compound of Formula B-1: R₂—Ar₂—R₂′  Formula B-1 wherein in Formula B-1, Ar₂ is

Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; R₂ and R₂′ are bonded to Ar₂₁ and Ar₂₂, respectively; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; R2 and R₂′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C2-30 alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and
 9. 5. The composition of claim 4, wherein the compound of Formula B-1 is a compound of any one of Formulae B-2 through B-23:

wherein in Formulae B-2 through B-23, R₂₁ and R₂₂ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group, in Formulae B-7 through B-9 and B-15 through B-20, X₁ is an oxygen atom or a sulfur atom; and in Formula B-14, X₂₁, X₂₂, X₂₃, X₂₄, X₂₅, X₂₆, X₂₇, and X₂₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group.
 6. The composition of claim 5, further comprising: a compound of Formula C-1: Ar₃

R₃)_(k3)  Formula C-1 wherein in Formula C-1 Ar₃ is

Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C1-60 heteroarylene group; at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are divalent arylene or divalent heteroarylene groups, R₃ is bonded thereto, Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl group or a substituted or unsubstituted heteroaryl group; Ar₃₅ and Ar₃₆ optionally form a ring together, Ar₃₇ and Ar₃₈ are each independently a hydrogen atom, a substituted or unsubstituted C₆₋₂₀ fused ring; R₃ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and k3 is an integer between 2 and
 4. 7. The composition of claim 6, wherein the compound of Formula C-1 is a compound of any one of Formulae C-2 through C-16:

wherein in Formulae C-2 through Formula C-16, R₃₁, R₃₂, R₃₃, and R₃₄ are each independently a hydrogen atom,

two or more of R₃₁, R₃₂, R₃₃, and R₃₄ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9; and in Formulae C-4 through C-9 and C-13 through C-16, X₁ and X₂ are each independently an oxygen atom or a sulfur atom.
 8. A composition for forming an organic film, comprising: a solvent; a compound of Formula D-1; and a compound of Formula E-3 or E-4:

wherein in Formula D-1, Ar₄ is

Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl group or a substituted or unsubstituted C₁₋₆₀ heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₄₂ and Ar₄₃ form a ring together; R₄ and R₄′ are bonded to Ar₄₂ and Ar₄₃, respectively; R₄ and R₄′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group, and j is an integer between 2 and
 9. 9. The composition of claim 8, wherein the compound of Formula D-1 is a compound of any one of Formulae D-2 through D-16:

wherein in Formulae D-2 through D-16, R₄₁ and R₄₂ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9; and in Formulae D-10 through D-16, X₁ is an oxygen atom or a sulfur atom.
 10. The composition of claim 1, further comprising: an initiator compound, wherein the solvent is methyl benzoate, the initiator compound is contained in an amount of about 0.5 wt % to 4.0 wt % with respect to the total weight of the composition for forming the organic film, and the initiator compound comprises a compound of any one of Formulae F-1, F-2, and F-3:


11. A display device, comprising: a base; anode electrodes on the base; a cathode electrode on the anode electrodes; and organic layers between the anode electrodes and the cathode electrode, wherein the organic layers comprise a polymer of a compound of Formula 1: Ar

R)_(k)  Formula 1 wherein in Formula 1, Ar is

Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene group or a substituted or unsubstituted C₁₋₁₂ heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ optionally form a ring together; two or more of Ar₁₃, Ar₁₄, and Ar₁₆ optionally form a ring together; Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl group or a substituted or unsubstituted C₁₋₁₀ heteroaryl group; Ar₃₅ and Ar₃₆ optionally form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl group or a substituted or unsubstituted C₃₋₆₀ heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₄₂ and Ar₄₃ form a ring together; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, at least one of Ar₁₇, Ar₁₈, and Ar₁₉, at least one of Ar₂₁, and Ar₂₂, at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄, and at least one of Ar₄₂, and Ar₄₃ are divalent arylene or divalent heteroarylene groups, R is bonded thereto; R is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and k is an integer between 2 and 4, and wherein in the polymer, the compound of Formula 1 are connected through a reaction product of R, wherein when Ar is

and when two or more of Ar₁₁, Ar₁₂, and Ar₁₅ form a ring together or when two or more of Ar₁₃, Ar₁₄, and Ar₁₆ form a ring together, R is


12. The display device of claim 11, wherein the organic layers comprise a first organic layer between the anode electrodes and the cathode electrode, and the first organic layer comprises a polymer of a compound of Formula A-1: Ar₃

R₃)_(k3)  Formula C-1 wherein in Formula A-1, Ar₁ is

Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₁₅ and Ar₁₆ are each independently a substituted or unsubstituted C₆₋₁₂ arylene group or a substituted or unsubstituted C₁₋₁₂ heteroarylene group; two or more of Ar₁₁, Ar₁₂, and Ar₁₅ optionally form a ring together, two or more of Ar₁₃, Ar₁₄, and Ar₁₆ optionally form a ring together, Ar₁₇, Ar₁₈, and Ar₁₉ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; at least one of Ar₁₁, Ar₁₂, Ar₁₃, and Ar₁₄, and at least one of Ar₁₇, Ar₁₈, and Ar₁₉ are divalent arylene or divalent heteroarylene groups, R₁ is bonded thereto; R₁ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; j is an integer between 2 and 9; and k1 is an integer between 2 and 4, wherein when Ar is

and when two or more of Ar₁₁, Ar₁₂, and Ar₁₅ form a ring together or when two or more of Ar₁₃, Ar₁₄, and Ar₁₆ form a ring together, R is


13. The display device of claim 12, wherein the display device comprises a first pixel configured to display a first color, a second pixel adjacent to the first pixel and configured to display a second color having a longer peak wavelength than the first color, and a third pixel adjacent to the first pixel and configured to display the first color, wherein the first organic layer in the first pixel is physically spaced apart from the first organic layer in the third pixel.
 14. The display device of claim 13, wherein the organic layers further comprise a second organic layer in the first pixel between the first organic layer and the cathode electrode, and the second organic layer comprises a polymer of compounds of Formulae B-2 and C-1: R₂—Ar₂—R₂′  Formula B-1 Ar₃

R₃)_(k3)  Formula C-1 wherein in Formula B-1, Ar₂ is

Ar₂₁ and Ar₂₂ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; R₂ and R₂′ are bonded to Ar₂₁ and Ar₂₂, respectively; X₁₁, X₁₂, X₁₃, X₁₄, X₁₅, X₁₆, X₁₇, and X₁₈ are each independently a hydrogen atom, a deuterium atom, a fluorine atom, a substituted or unsubstituted C₁₋₁₀ alkyl group, a substituted or unsubstituted C₃₋₁₀ cycloalkyl group, a substituted or unsubstituted C₁₋₂₀ alkoxy group, a substituted or unsubstituted C₃₋₃₀ alkylsilyl group, a substituted or an unsubstituted C₆₋₃₀ aryl group, a substituted or unsubstituted C₆₋₂₀ aryloxy group, a substituted or unsubstituted C₈₋₃₀ arylsilyl group, or a substituted or unsubstituted C₅₋₃₀ heteroaryl group; R7 and R₂′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group; and j is an integer between 2 and 9; and in Formula C-1, Ar₃ is

Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ are each independently a substituted or unsubstituted C₆₋₆₀ aryl group, a substituted or unsubstituted C₆₋₆₀ arylene group, a substituted or unsubstituted C₁₋₆₀ heteroaryl group, or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; at least one of Ar₃₁, Ar₃₂, Ar₃₃, and Ar₃₄ is a divalent arylene or divalent heteroarylene group, R₃ is bonded thereto, Ar₃₅ and Ar₃₆ are each independently a hydrogen atom or a substituted or unsubstituted C₆₋₁₀ aryl group or a substituted or unsubstituted heteroaryl group, Ar₃₅ and Ar₃₆ optionally form a ring together; Ar₃₇ and Ar₃₈ are each independently a substituted or unsubstituted C₆₋₂₀ fused ring; R₃ is

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group, j is an integer between 2 and 9, and k3 is an integer between 2 and
 4. 15. The display device of claim 14, wherein the organic layers further comprise a third organic layer in the second pixel between the first organic layer and the cathode electrode, and the third organic layer comprises a polymer of a compound of Formula D-1: R₄—Ar₄—R₄′  Formula D-1 wherein in Formula D-1, Ar₄ is

Ar₄₁ is a substituted or unsubstituted C₆₋₆₀ aryl group or a substituted or unsubstituted C₁₋₆₀ heteroaryl group; Ar₄₂ and Ar₄₃ are each independently a substituted or unsubstituted C₆₋₆₀ arylene group or a substituted or unsubstituted C₁₋₆₀ heteroarylene group; Ar₄₂ and Ar₄₃ form a ring together; R₄ and R₄′ are bonded to Ar₄₂ and Ar₄₃, respectively; R₄ and R₄′ are each independently

R₀ is a substituted or unsubstituted C₁₋₃₀ alkyl group, a substituted or unsubstituted C₃₋₃₀ cycloalkyl group, a substituted or unsubstituted C₃₋₃₀ heterocycloalkyl group, a substituted or unsubstituted C₂₋₃₀ alkenyl group, a substituted or unsubstituted C₂₋₃₀ alkynyl group, a substituted or unsubstituted C₆₋₃₀ aryl group, or a substituted or unsubstituted C₃₋₃₀ heteroaryl group, and j is an integer between 2 and
 9. 16. The display device of claim 15, wherein the organic layers further comprise a fourth organic layer between the second organic layer and the cathode electrode and between the third organic layer and the cathode electrode, and the fourth organic layer in the first pixel is physically formed in one integral body with the fourth organic layer in the third pixel.
 17. A method of manufacturing a display device, the method comprising: forming a coating layer by coating a base with the composition of claim 1; and forming organic layer patterns by patterning the coating layer.
 18. The method of claim 17, wherein the forming of the organic layer patterns comprises: placing a mask having openings over the coating layer, partially exposing and curing the coating layer by applying light, and developing the cured coating layer utilizing a developer.
 19. The method of claim 18, further comprising, before the forming of the coating layer: forming an electrode layer on the base; and forming a bank having openings to expose a surface of the electrode layer.
 20. The method of claim 18, further comprising, after the forming the organic layer patterns: forming a bank having openings to expose the surfaces of the organic layer patterns. 